CO<sub>2</sub> Hydrogenation to Higher Alcohols over K-Promoted Bimetallic Fe–In Catalysts on a Ce–ZrO<sub>2</sub> Support

نویسندگان

چکیده

Novel K-promoted bimetallic Fe- and In-based catalysts on a Ce? ZrO2 support were prepared tested for higher alcohol synthesis from CO2 hydrogen. The FeIn/Ce?ZrO2 precursors with different Fe contents characterized in detail, well-dispersed Fe2O3 In2O3 phases oxygen vacancies observed. continuous setup at extended times stream (up to 100 h) 300 °C, 10 MPa, gas hourly space velocity of 4500 mL g?1 h?1, H2/CO2 ratio 3. effect K loading, the pretreatment atmosphere, Fe/(Fe + In) molar ratios, calcination temperature conversion product selectivity studied. Best performance 29.6% 28.7%, together good stability, was obtained over K-0.82-FeIn/Ce?ZrO2_900 catalyst after activation under CO atmosphere. These findings rationalized by considering effects individual components (K, Fe, performance. Surprisingly, presence calcined SiC, used as diluent packed bed reactor, shown have positive such also is catalytically active. best terms yield (8.5%) this work ranks top three reports hydrogenation alcohols setup. Moreover, light olefins 20.3% (6.0% yield) coproduced optimized catalyst, which has economic potential catalysts.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Hydrogenation of carbon monoxide over vanadium oxide- promoted rhodium catalysts

The effect of vanadium oxide as support and promoter on supported rhodium catalysts on the CO hydrogenation has been investigated at 0.15 and 4.0 MPa. Rh/V,O, reduced at 723 K has a good selectivity toward oxygenated products, especially C,-oxygenates, but has a low activity added as a promoter to catalysts consisting and stability. Vanadium oxide of rhodium supported on silica and alumina show...

متن کامل

Transfer hydrogenation of cellulose to sugar alcohols over supported ruthenium catalysts.

Ru/C catalysts are active for the conversion of cellulose using 2-propanol or H(2) of 0.8 MPa as sources of hydrogen, whereas the Ru/Al(2)O(3) catalyst is inactive in both reactions, indicating that the Ru/C catalysts are remarkably effective for the cellulose conversion.

متن کامل

A comparative study on the kinetics of carbon dioxide methanation over bimetallic and monometallic catalysts

In this paper, Ni/Al and La-Ni/Al catalysts were prepared with a co-impregnation method and employed in carbon dioxide methanation reaction. The catalytic results showed that the catalyst with (10wt.%) of lanthanum and (20wt.%) nickel had the highest activity at low temperatures in CO2 methanation and the La-Ni/Al catalysts changed the reaction path by lowering its activation energy and consequ...

متن کامل

Cobalt Loading Effects on the Physico-Chemical Properties and Performance of Co Promoted Alkalized MoS2/CNTs Catalysts for Higher Alcohols Synthesis

An extensive study of Higher Alcohol Synthesis (HAS) from synthesis gas using cobalt (Co) promoted alkalized MoS2 catalysts supported on Carbon NanoTubes (CNTs) is reported. Up to  5wt.% of Co is added to the 15wt.% Mo-wt.%K/ CNTs by incipient wetness impregnation method. Most of the metal particles were homogeneously distributed inside the tubes and the rest on the oute...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: ACS Sustainable Chemistry & Engineering

سال: 2021

ISSN: ['2168-0485']

DOI: https://doi.org/10.1021/acssuschemeng.0c08760